Elsevier

Journal of Alloys and Compounds

A flexible metallic sparse motion-picture show strain sensor with micro/nano construction for large deformation and high sensitivity strain measurement

Abstract

Flexible strain sensors take been garnering substantial attention since being proven to be an effective means to acquire critical biomarkers for monitoring the states of the motility of organisms. This work introduces a flexible metal sparse film strain sensor with micro/nano structure which has big measurement range and loftier sensitivity strain measurement. The large measurement range tin can exist realized by the bugles that fugitive expanding of cracks and the loftier sensitivity is attributed to the disconnection-reconnection process by nanoscale cracks. In experiments, a flexible strain sensor with thirty nm Au nano-film was researched, and the results testify that the maximum strain measurement range of the Au nano-film flexible sensor with micro/nano bulge structure can reach to eighty%, and the gauge cistron (
GF) can achieve to twenty. In addition, the practiced repeatability and stability were proved by more than yard times cycles. Finally, this flexible sensor was fastened to man’s fingers for real-time monitoring of the land of human joints and was demonstrated to take skilful comprehensive performance and usability. These features create opportunities for applying in many fields like vesture medical devices, e-skin, flexible robots and and so on.

Introduction

With the rapid development of wearable medical devices [one], [ii], [3], [4], [5], electronic skin and high-performance sensors [6], [7], [eight], [9], sensors are increasingly needed to mensurate strain (stress) signals with large deformation and high sensitivity [ten]. Nevertheless, although micrometer-thick metals [11], [12] or semiconductor materials [thirteen], [14] are mostly used as sensitive materials for metal foil strain gauges and piezoresistive sensors, measuring large strains (>5%) is also difficult and challenging. Therefore, studies on the high sensitive and large deformation flexible strain sensors for article of clothing devices, medical health monitoring and bio-robotics applications have attracted considerable interest.

Many studies already produced high-operation flexible strain sensor, using various types of sensitive materials, such as carbon nanotubes [15], [16], [17], graphene [xviii], [19], ZnO nanowires [20], [21], and C-fibers [22], [23], which are combined with flexible polymer (PDMS, Ecoflex or epoxy resin) substrates to realize large strain range and high sensitivity coefficient. However, this method has special sensitive materials, complex training processes and high costs. Besides, micro/nano cracks [24], [25], [26], [27] were applied to heighten the sensitivity of flexible sensors in some references while the existence of cracks influenced the measurement range of flexible sensors. A flexible nano-scale-cracks sensor [26] with a sensitivity ratio of every bit high as 2000 and strain measurement limit of only 1%. To increase the measurement range of the sensor, some researchers [28], [29], [30] have made strain sensors with regular micro/nano folds by using micro/nano fabrication techniques, of which the ultimate strain tin can reach up to 100%. However, the beingness of micro/nano folds results in low sensitivity coefficient in small deformation measurements. Therefore, it is important that using a simple and low-price method to fabricate flexible and high sensitivity strain sensors which can work under either small-scale or large deformation.

Harmless metals such as Cu and Au are the most commonly used and the oldest sensitive fabric in strain sensors [31], [32] because is stable, simple, inexpensive, and convenient and exhibit reliable functioning and capacity for mature processes. Thus, information technology is used for fabricating sensitive structures on various substrates mostly past common processes of sputtering, evaporation, machining and welding, as shown in Fig. 1(b). However, the usually used bulk metal only has a limited elastic strain range and is hard to employ in large deformation measurements. Another unremarkably used polymer material is polyurethane (PU), which has a large elastic range, is inexpensive, and has skillful biological compatibility [33], [34], [35]. It has been widely used in clinical bandage dressing equally shown in Fig. one(a). Therefore, the two materials are combined in this study. Specifically, we use PU picture with micron thickness equally the substrate to achieve large strain deformation, and utilize nano metallic sparse film as strain sensing material to accomplish loftier sensitivity, where we utilise a combination of micro/nano cleft and micro/nano structure with bulges to obtain high-sensitivity strain sensing in the condition of the big deformations. The schematic diagram of the strain sensor is shown in Fig. 1(c). The structure of the strain sensor is simple, and the major part is only composed of a flexible substrate material and nano metallic thin films with micro/nano bulges and micro/nano cracks, which makes the strain sensor realize large measurement range and highly sensitive. And the specific analysis and explanation can be observed in the sensor’s conductive model in minor and big strains, as shown in Fig. 1(d) and (e). The mechanism of the flexible sensor could state as follows. The loftier sensitivity of the flexible sensor is due to the meaning resistance change of the AU nano-moving picture acquired by the cracks disconnection-reconnection process. The large measurement range is due to the bugles which blocked the expansion of micro/nano cracks and formed many brusque cracks.

Section snippets

Fabrication of PU film with flexible micro/nano bulge structures

A simple and low-cost manufacturing method of flexible strain sensors with micro/nano bulge structures by using tear and stick was proposed in Fig. ii. A low-cost PU picture that exhibits skillful biological compatibility and is commonly used in clinic was adopted (50 µm thickness, produced by Lian Yun Gang Zhengrui Medical Devices Company) equally flexible substrate materials. The film was covered by a PE protective moving-picture show and was stuck to the release paper, and then was cutting into twenty mm × ten mm rectangles, equally

Results and discussion

Fig. 2 shows the fabrication process of the flexible sensor, the detailed steps are shown in the Experimental part. Fig. 3(a) shows the scanning electron microscope (SEM) images of the sensors that take not been stretched, where six cracks were randomly selected from the surface of the sensors. The boilerplate width of the scissure is 140 nm. And then, the sensor is stretched to xl% and lxxx% strain respectively. Similarly, nosotros randomly select 6 cracks, and the average widths of the cracks are 439 nm and

Conclusions

A flexible metal thin moving picture strain sensor with micro/nano bulge construction for big deformation and high sensitivity strain measurement is proposed. The structure of the sensor is very uncomplicated, which is composed of the sensitive element and the substrate. The substrate of the sensor is a depression-price PU moving picture with skilful biological compatibility. The sensitive element is a nano-metal moving picture which is made by the common processing applied science of sputtering. The micro/nano structure of the flexible

CRediT authorship contribution argument

Junfang Shu: Conceptualization, Data curation, Formal analysis, Investigation, Writing – original draft.
Ruirui Yang: Information curation, Formal analysis, Investigation, Software, Visualization, Writing – revised.
Yongqin Chang: Project administration, Resources, Supervision, Writing – review & editing.
Xingqi Guo: Methodology, Data curation, Writing – review & editing.
Xing Yang: Conceptualization, Funding acquisition, Projection administration, Resources, Supervision, Writing – review & editing.

Declaration of Competing Interest

The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the piece of work reported in this newspaper.

Acquittance

This work was financially supported by
National Natural Science Foundation of Red china
Project (Grant Nos.
52075291
and
51735007
).

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